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Thermal and Spectral Characterization of Cr(III), Co(II) and Cd(II) Metal Complexes Containing Bis-Imine Novel Schiff Base Ligand Towards Potential Biological Application

Received: 7 January 2017     Accepted: 21 January 2017     Published: 24 February 2017
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Abstract

Metal complexes of Cr(III), Co(II) and Cd(II) ions were synthesizedwith a ONS containing Schiff base ligand, 2-bis(2-oxoindolin-3-ylidene)hydrazinecarbothioamide which was derived from the condensation reaction of thiosemicarbazide and isatin. The ligand and complexes were isolated from the reaction in the solid form and characterized by IR, UV-Visible, Thermal analysis and some physical measurements. Spectroscopic evidence indicated that the Schiff base behaved as ONS coordinating hexadentate chelating agent. Magnetic susceptibility data coupled with electronic spectra suggested a distorted octahedral structure of the complexes. The overall reaction was monitored by TLC and UV-Visible spectral analysis. The Schiff base and their metal complexes have been shown moderate to strong microbial activity.

Published in Chemical and Biomolecular Engineering (Volume 2, Issue 1)
DOI 10.11648/j.cbe.20170201.16
Page(s) 41-50
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This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2017. Published by Science Publishing Group

Keywords

Transition Metal Complex, IR, UV-Visible Spectra Analysis, Antibacterial Activity, Schiff Base, TGA and DTG

References
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    Md. Saddam Hossain, Shudeepta Sarker, A. S. M. Elias Shaheed, Md. Mamun Hossain, Abdul Alim-Al-Bari, et al. (2017). Thermal and Spectral Characterization of Cr(III), Co(II) and Cd(II) Metal Complexes Containing Bis-Imine Novel Schiff Base Ligand Towards Potential Biological Application. Chemical and Biomolecular Engineering, 2(1), 41-50. https://doi.org/10.11648/j.cbe.20170201.16

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    ACS Style

    Md. Saddam Hossain; Shudeepta Sarker; A. S. M. Elias Shaheed; Md. Mamun Hossain; Abdul Alim-Al-Bari, et al. Thermal and Spectral Characterization of Cr(III), Co(II) and Cd(II) Metal Complexes Containing Bis-Imine Novel Schiff Base Ligand Towards Potential Biological Application. Chem. Biomol. Eng. 2017, 2(1), 41-50. doi: 10.11648/j.cbe.20170201.16

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    AMA Style

    Md. Saddam Hossain, Shudeepta Sarker, A. S. M. Elias Shaheed, Md. Mamun Hossain, Abdul Alim-Al-Bari, et al. Thermal and Spectral Characterization of Cr(III), Co(II) and Cd(II) Metal Complexes Containing Bis-Imine Novel Schiff Base Ligand Towards Potential Biological Application. Chem Biomol Eng. 2017;2(1):41-50. doi: 10.11648/j.cbe.20170201.16

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  • @article{10.11648/j.cbe.20170201.16,
      author = {Md. Saddam Hossain and Shudeepta Sarker and A. S. M. Elias Shaheed and Md. Mamun Hossain and Abdul Alim-Al-Bari and Md. Rabiul Karim and C. M. Zakaria and Md. Kudrat-E-Zahan},
      title = {Thermal and Spectral Characterization of Cr(III), Co(II) and Cd(II) Metal Complexes Containing Bis-Imine Novel Schiff Base Ligand Towards Potential Biological Application},
      journal = {Chemical and Biomolecular Engineering},
      volume = {2},
      number = {1},
      pages = {41-50},
      doi = {10.11648/j.cbe.20170201.16},
      url = {https://doi.org/10.11648/j.cbe.20170201.16},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.cbe.20170201.16},
      abstract = {Metal complexes of Cr(III), Co(II) and Cd(II) ions were synthesizedwith a ONS containing Schiff base ligand, 2-bis(2-oxoindolin-3-ylidene)hydrazinecarbothioamide which was derived from the condensation reaction of thiosemicarbazide and isatin. The ligand and complexes were isolated from the reaction in the solid form and characterized by IR, UV-Visible, Thermal analysis and some physical measurements. Spectroscopic evidence indicated that the Schiff base behaved as ONS coordinating hexadentate chelating agent. Magnetic susceptibility data coupled with electronic spectra suggested a distorted octahedral structure of the complexes. The overall reaction was monitored by TLC and UV-Visible spectral analysis. The Schiff base and their metal complexes have been shown moderate to strong microbial activity.},
     year = {2017}
    }
    

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  • TY  - JOUR
    T1  - Thermal and Spectral Characterization of Cr(III), Co(II) and Cd(II) Metal Complexes Containing Bis-Imine Novel Schiff Base Ligand Towards Potential Biological Application
    AU  - Md. Saddam Hossain
    AU  - Shudeepta Sarker
    AU  - A. S. M. Elias Shaheed
    AU  - Md. Mamun Hossain
    AU  - Abdul Alim-Al-Bari
    AU  - Md. Rabiul Karim
    AU  - C. M. Zakaria
    AU  - Md. Kudrat-E-Zahan
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    PY  - 2017
    N1  - https://doi.org/10.11648/j.cbe.20170201.16
    DO  - 10.11648/j.cbe.20170201.16
    T2  - Chemical and Biomolecular Engineering
    JF  - Chemical and Biomolecular Engineering
    JO  - Chemical and Biomolecular Engineering
    SP  - 41
    EP  - 50
    PB  - Science Publishing Group
    SN  - 2578-8884
    UR  - https://doi.org/10.11648/j.cbe.20170201.16
    AB  - Metal complexes of Cr(III), Co(II) and Cd(II) ions were synthesizedwith a ONS containing Schiff base ligand, 2-bis(2-oxoindolin-3-ylidene)hydrazinecarbothioamide which was derived from the condensation reaction of thiosemicarbazide and isatin. The ligand and complexes were isolated from the reaction in the solid form and characterized by IR, UV-Visible, Thermal analysis and some physical measurements. Spectroscopic evidence indicated that the Schiff base behaved as ONS coordinating hexadentate chelating agent. Magnetic susceptibility data coupled with electronic spectra suggested a distorted octahedral structure of the complexes. The overall reaction was monitored by TLC and UV-Visible spectral analysis. The Schiff base and their metal complexes have been shown moderate to strong microbial activity.
    VL  - 2
    IS  - 1
    ER  - 

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Author Information
  • Department of Chemistry, University of Rajshahi, Rajshai, Bangladesh

  • Department of Chemistry, University of Rajshahi, Rajshai, Bangladesh

  • Department of Chemistry, University of Rajshahi, Rajshai, Bangladesh

  • Department of Pharmacy, University of Rajshahi, Rajshai, Bangladesh

  • Department of Pharmacy, University of Rajshahi, Rajshai, Bangladesh

  • Department of Chemistry, University of Rajshahi, Rajshai, Bangladesh

  • Department of Chemistry, University of Rajshahi, Rajshai, Bangladesh

  • Department of Chemistry, University of Rajshahi, Rajshai, Bangladesh

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